G. Ramesh, Marri Pradeep Kumar, A. Rambabu
May 21, 2018
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Abstract
A series of [Co(L I )2] (1), [Ni(L I )2] (2), [Cu(L I )2] (3), [Co(L II )2] (4), [Ni(L II )2] (5) and [Cu(L II )2] (6) complexes where L I = 2-((E)-(5-(4-fluorophenyl)isoxazol-3-ylimino)methyl)-5-methoxyphenol and L II = 2-((E)-(5-(4-fluorophenyl)isoxazol-3-ylimino)methyl)-4-bromophenol, were synthesized and characterized by elemental analysis, Infrared, UV–visible, Nuclear magnetic resonance, Mass spectral studies, Electron Spin Resonance, Thermogravimetric analysis, Magnetic moment, Scanning Electron Microscope and Powder X-ray Diffraction analyses. From the analytical results, all these metal (II) complexes are assigned to square planar geometry around the metal ions. The DNA-binding and cleavage studies were evaluated for the synthesized compounds with CT–DNA and supercoiled pBR322 DNA, respectively. All compounds have been monitored for their in Vitro antimicrobial assay. Original Research Article Ramesh et al.; AJOCS, 4(3): 1-20, 2018; Article no.AJOCS.41465 2