G. Devoto, M. Biddau, M. Massacesi
Dec 1, 1983
Citations
0
Influential Citations
7
Citations
Journal
Journal of Inorganic Biochemistry
Abstract
Abstract Palladium(II) oxalato complexes with heterocyclic ligands have been prepared and characterized by spectroscopic and biological studies. The compounds are of the general formula Pd(ox)(L) n where ox = oxalato For n = 1, the ligand is isoxazole, 3,5-dimethylisoxazole, 2-methyl-benzoxazole, 2,5-dimethylbenzoxazole, and ethylenediamine, for n = 2, the ligand is N methylimidazole, N -ethylimidazole, N -propylimidazole, 3-amino, 5-methylisoxazole, and 5-amino 3,4 dimethylisoxazole. The Pd(ox)(L) 2 soluble in water are monomeric square-planar; the Pd(ox)(L) that are little soluble in water are dimeric square-planar with the ligand bridging bidentate except to the chelate ethylenediamine. All the compounds exhibit a certain inhibitorial effect with the exception of the Pd(ox)(en) derivative.