A. Haider, Z. Akhter, F. Jabeen
May 17, 2011
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Influential Citations
8
Citations
Journal
Journal of Molecular Structure
Abstract
Abstract The dinitrocompound, 1,4-bis((4-nitrophenoxy)methyl)benzene (NMB) and its derivative 1,4-bis((4-aminophenoxy)methyl)benzene (AMB), a potential monomer for polymeric materials have been synthesized and characterized by elemental and spectral studies. AMB was also characterized by single crystal analysis as the monoclinic space group C2/c with unit cell parameters a = 40.858(6) A, b = 5.4606(8) A, c = 7.7741(15) A; α = 90°, β = 100.471(7)°, γ = 90° and Z = 4. The molecule is located on a centre of inversion and the water molecule on a twofold rotation axis. The cyclic voltammetric (CV) investigations showed the precursor and its amino-analogue to be strong ds.DNA binder and replication quencher. The threading intercalation mode of binding is proposed on the basis of positive peak potential shift and molecular structures.