V. Minkin, A. A. Maksimenko, G. K. Mehrotra
Jun 28, 1988
Citations
0
Influential Citations
15
Citations
Journal
Journal of Organometallic Chemistry
Abstract
Abstract A wide series of diorganyldiaryloxytelluranes having an azomethine function in the position ortho to the tellurium atom have been synthesized by the reaction of diorganyldimethoxytelluranes with benzylidene- o -aminophenols. The X-ray structural investigation of the dimethylbis[2-(4-nitrobenzylideneimino)phenyloxy]tellurane indicates the presence of an intramolecular coordination bond Te ⋯ N. According to the dipole moment data and the 1 H, 125 Te, 14 N NMR spectra, in compounds VII, excluding those having nitro groups in the position para to the CHN bond, the Te ⋯ N coordination is retained in a non-polar solvent (benzene).