N. Mincheva, T. Todorov, O. Angelova
Jun 1, 2000
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0
Influential Citations
11
Citations
Journal
Journal of Coordination Chemistry
Abstract
Abstract The formation of two complexes by reaction of [PdCl4]2- with 1,2,3-triphenylguanidine (PhNH)2C=NPh under different metal/ligand ratios has been observed and the structure of the complex [(1,2,3-triphenylguanidine)2PdCl2] has been determined by X-ray diffraction methods. The ligands are coordinated as neutral monodentate molecules to the metal centre through their imine nitrogen atoms. The second Pd(II) complex is [Pd(1,2,3-triphenylguanidine)4]2+ and was isolated by precipitation with ClO− 4.