Gui Li, Wei Wang, Shu Hua Zhang
Jul 12, 2014
Citations
0
Influential Citations
10
Citations
Journal
Journal of Cluster Science
Abstract
The solvothermal assembly of Co(OAc)2·4H2O with 5-fluoro-2-hydroxy-benzoic acid (H2fhba) and 1,10-Phenanthroline (phen) yielded a new linear trinuclear cobalt cluster, [Co3(Hfhba)2(phen)2 (μ2-OAc)4] (1). The complex 1 was characterized by IR spectroscopy, elemental analysis and X-ray single-crystal diffraction. The study of magnetic properties indicates that antiferromagnetic coupling interactions exist between the adjacent Co(II) ions. So the 5-fluoro-2-hydroxy-benzoic acid participates in transferring magnetic interaction for the first time.