S. Sasaki, K. Sasaki, M. Yoshifuji
Jan 14, 2008
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Influential Citations
12
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Journal
Phosphorus, Sulfur, and Silicon and the Related Elements
Abstract
Tris(2,6-diisopropyl-4-methoxyphenyl)phosphine (1) was synthesized to investigate substituent effect of methoxy groups on the properties of crowded triarylphosphines. Methoxy groups slightly lower the first oxidation potential of 1 and contribute blue-shift of UV-Vis absorption as compared with the corresponding 2,4,6-triisopropylphenyl derivative.