V. Sharutin, O. Sharutina
Sep 28, 2016
Citations
0
Influential Citations
3
Citations
Journal
Russian Journal of General Chemistry
Abstract
The interaction of tris(4-fluorophenyl)antimony with copper(II) bromide in acetone has afforded tris(4-fluorophenyl)antimony dibromide; recrystallization of the product from ethanol has yielded the (4-FC6H4)3SbBr2·[(4-FC6H4)3SbBr]2O adduct. [(4-FC6H4)3SbCNS]2O oxide has been prepared from tris(4-fluorophenyl)antimony dibromide and potassium thiocyanate in aqueous-acetone solution. Antimony atoms in the molecules of the prepared compounds exhibited the distorted trigonal bipyramid coordination with the electron-accepting ligands in the axial positions.