Juan Cámpora and, M. L. Reyes, K. Mereiter
Feb 12, 2002
Citations
0
Influential Citations
14
Citations
Journal
Organometallics
Abstract
Homoleptic group 10 aryloxides consisting of discrete molecules have been isolated from the reaction of the sodium salts of bulky phenols with NiBr2(dme) or PdCl2(MeCN)2. The nickel 2,6-diisopropylphenolate is a trimer, displaying σ-coordinated aryloxide ligands, while the Ni and Pd derivatives of 2,6-di-tert-butylphenol are monomers that adopt an unprecedented π-allylic, sandwich-like structure.