Lili Wen, Fang‐Ming Wang, Xiao-Ke Leng
Mar 20, 2010
Citations
0
Influential Citations
13
Citations
Journal
Journal of Inorganic and Organometallic Polymers and Materials
Abstract
Hydrothermal and solution reactions of pyridine-2,6-dicarboxylic acid N-oxide (2,6-PDCO) and BaCl2·2H2O yield two metal–organic frameworks; namely [Ba(2,6-PDCO)]n (1) and [Ba(2,6-PDCO)·H2O]n (2), respectively. Single-crystal X-ray analyses reveal that compound 1 is a dense framework whereas compound 2 is a porous one, though both compounds have an infinite two-dimensional (2D) layer structure. Compounds 1 and 2 are the first examples of pyridine dicarboxylic acid N-oxide introduced into the alkaline earth metal–organic framework.