M. Munakata, S. Kitagawa, Naohiko Ujimaru
Mar 1, 1993
Citations
0
Influential Citations
58
Citations
Journal
Inorganic Chemistry
Abstract
Three copper(I) and two silver(I) complexes with phenazine (phz), [Cu 2 (phz) 3 (MeOH) 2 ](phz)(PF 6 ) 2 (1), [Cu-(Phz) 2 (H 2 O)]ClO 4 (2), [Cu(Phz) 2 (NO 3 )] (3), {[Ag(Phz)]ClO 4 } ∞ (4), and [Ag 2 (phz)(NO 3 ) 2 ] ∞ (5), were synthesized and their molecular structures and packings were determined by using single-crystal X-ray diffraction methods. 1 is composed of infinite stacks of alternating metal-free phz molecules and the dicopper complex cations [Cu 2 -(phz) 3 (MeOH) 2 ] 2+ and gives a CT band from the latter to the former at 710 nm indicative of a donor-acceptor complex