Masaaki Suzuki, I. Son, R. Noyori
Dec 1, 1990
Citations
0
Influential Citations
20
Citations
Journal
Organometallics
Abstract
Chloro- and (2,6-dimethylphenoxy)triorganostannanes react with tris(dimethylamino)sulfonium (TAS) chloride or 2,6-dimethylphenoxide in acetonitrile to form the corresponding pentacoordinate stannate complexes. The solution-phase behavior and solid-state structures of the TAS stannates have been examined by use of NMR and far-infrared spectroscopy, Mossbauer measurements, and X-ray crystallography, revealing the hypervalent nature of the anionic Sn(IV) species with trigonal-bipyramidal structures