W. Setzer, Show-Yee Liou, G. Easterling
1998
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0
Influential Citations
3
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Journal
Heteroatom Chemistry
Abstract
The functionalized mesocyclic trithioethers, 1,4,7-trithiacyclodecane-9,9-dimethanol (10S3-diMeOH), 9 -methyl-1, 4, 7 - trithiacyclodecane - 9 -carboxylic acid (Me-10S3-acid), 1,4,7-trithiacycloundecane-9,10-diol (dihydroxy-11S3), 1,5,9-trithiacyclododecane-3,3-dimethanol (12S3-diMeOH), 3-methyl-1,5,9-trithiacyclododecane-3-carboxylic acid (Me-12S3-acid), and 1 , 5 , 9 - trit hiacyclo tride cane -11 , 12 - diol ( dihydroxy - 13S3), have been synthesized using the cesium dithiolate technique. The single-crystal X-ray structure has been determined for 3-methyl-1,5,9-trithiacyclododecane-3-carboxylic acid. The compound crystallizes in the monoclinic space group P21/n, with a = 9.513(2) A, b = 5.706(1) A, c = 25.70(1) A, β = 96.50(1)°, Z = 4, and R = 0.075. © 1998 John Wiley & Sons, Inc. Heteroatom Chem 9:123–128, 1998