Bw Au-Yeung, T. Chan, S. Tam
1975
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0
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1
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Journal
Australian Journal of Chemistry
Abstract
The syntheses of 2-(2?,4?-dihydroxy-6?-methylbenzoyl)-3,6- dihydroxybenzoic acid (4) and its methyl ethers are described. Treatment of 6-hydroxy-2-(2?-hydroxy-4?-methoxy-6?-methylbenzoyl)-3- methoxybenzoic acid (8) with alcoholic potassium hydroxide gave 2- hydroxy-6-methoxy-8-methyl-9-oxoxanthene-1-carboxylic acid (9). Comparison of the p.m.r. spectra of these structurally related 2- benzoylbenzoic acids revealed that the chemical shifts of the aryl methyl and the ring protons are significantly influenced by the existence of intramolecular hydrogen bonding.