W. Oppolzer, O. Froelich, C. Wiaux‐Zamar
Apr 21, 1997
Citations
0
Influential Citations
31
Citations
Journal
Tetrahedron Letters
Abstract
Bornane-10,2-sultam 1 is stereoselectively converted by DMAP-assisted sulfinylation to diastereomerically pure (2 R )- N -[( R )- p -tolylsulfinyl]-bornane-10,2-sultam 2 in 77% yield. The crystalline sulfinylating agent 2 reacts with a variety of nucleophiles to afford sulfoxides 3 and sulfinimines 5 in excellent yields and enantioselectivities.