I. Sheikhshoaie, S. Y. Ebrahimipour, A. Crochet
Apr 1, 2015
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Influential Citations
18
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Journal
Research on Chemical Intermediates
Abstract
Reaction of 4-bromo-2-(((5-chloro-2-hydroxyphenyl) imino)methyl)phenol (H2L) with VOSO4·XH2O generates the oxido-vanadium(V) complex [VOL(OCH3)(OHCH3)], that characterized by FT-IR, UV–Vis, and elemental analysis. The complex was also characterized by single crystal X-ray diffraction crystallography. A DFT calculation was carried out on the complex using the B3LYP/6-31+G(d,p) method. The agreement between the theoretical and experimental data is good. NBO data shows that the donation from donor atoms to the metal center is greater than back bonding.