V. Nesterov, S. S. Nagapetyan, V. E. Shklover
Sep 1, 1995
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Journal
Russian Chemical Bulletin
Abstract
The structure of bis(2-sodiumsulfonylethyl) sulfoxide hexahydrate (1), which was synthesized by the reaction of divinyl sulfoxide with sodium metabisulfite in an aqueous ethanol medium, has been determined by X-ray structural analysis. Both Na+ cations are coordinated by six O atoms of crystallization water molecules and SO3 groups; the coordination sphere is a distorted octahedron. The crystals are stabilized by an extensive network of hydrogen bonds through the water molecules of crystallization.