C. You
2012
Citations
0
Influential Citations
0
Citations
Journal
Chinese Journal of Spectroscopy Laboratory
Abstract
The flexible ligand with two imidazole,[1,3-bis(imidazol-1-ylmethyl)benzene dihydrate] was synthesize by imidazole and 1,3-bis(chloromethyl) benzene.The ligand was characterized by IR,1H NMR and elemental analysis,and the structure was identified by X-ray single crystal diffraction analysis.The results showed that the compound belongs to monoclinic,space group C2,its cell parameters were as follows:a=1.6852(6)nm,b=0.9529(3)nm,c=0.46494(16)nm,β=100.552(4)°,V=0.7340(4)nm3,Z=2,Dc=1.241g·cm-3,F(000)=292,μ=0.086mm-1,R1=0.0323,wR2=0.0826.HF/6-31G(d) method was used for theoretical analysis of the structure,it proves that terminal N atom of the ligand has high activity,that is easy to coordinate to metal atoms.