R. Khusnutdinov, N. A. Shchadneva, T. M. Oshnyakova
Nov 20, 2011
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Journal
Petroleum Chemistry
Abstract
The telomerization of 1Z,5Z-cyclooctadiene with halogenated methanes (CCl4, CBrCl3, CHCl3, CH2Cl2) mediated by chromium, copper, and molybdenum complexes has been investigated. It has been shown that the use of water as a nucleophilic additive promotes the formation of 1,4- and 1,5-epoxycyclooctanes and anti-8-(trichloromethyl)bicyclo[3.2.1]octan-exo-2-ol.