Suvankar Debbarma, S. S. Bera, M. Maji
Nov 17, 2016
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0
Influential Citations
23
Citations
Journal
The Journal of organic chemistry
Abstract
The readily synthesized trichloro acetimidamide was found to be an excellent directing group for the directed C-H-allylation reactions. Depending on the allylating agent used, selectively either mono- or diallylated products were readily synthesized. Moreover, the trichloro acetimidamide directing group was found to be highly efficient even at lower temperature for the C-H-allylation reaction. Due to mildness of the reaction conditions, double bond isomerization or cyclization to indole side product was not observed.