K. Zherikova, L. N. Zelenina, D. Pishchur
Nov 1, 2016
Citations
0
Influential Citations
10
Citations
Journal
The Journal of Chemical Thermodynamics
Abstract
Abstract Complex of rhodium(III) with acetylacetone (Rh(acac)3) was synthesized, purified and identified for thermochemical study. Vapor pressures of the compound were measured by static and transpiration methods in the temperature range from 398 to 521 K. Thermodynamic characteristics of sublimation process ΔsubH459.6 and ΔsubS°459.6 were determined from the experimental data. Heat capacity in the temperature range from 188 to 465 K was measured by using DSC for the first time. Using experimental results, ΔsubH298.15 and ΔsubS°298.15 of the compound were derived.