J. Mccullough, D. W. Scott
Mar 1, 1959
Citations
0
Influential Citations
6
Citations
Journal
Journal of the American Chemical Society
Abstract
In a continuation of thermodynamic studies of monoolefins, values of the following thermodynamic properties of 2-methyl-1-butene were computed at selected temperatures between 0 and 1500/sup 0/K: (F/sup 0/ - H/sub 0//sup 0/)/T, (H/sup 0/ - H/sub 0//sup 0/)/T, H/sup 0/ - H/sub 0//sup 0/, S/sup 0/, C/sup 0//sub p/, ..delta..Ff/sup 0/ and log Kf. A detailed vibrational and conformational analysis showed that the compound exists in two spectroscopically distinct conformations, one of which is predominant at room temperature.