D. W. Scott, G. Waddington, J. C. Smith
Aug 1, 1949
Citations
0
Influential Citations
27
Citations
Journal
Journal of the American Chemical Society
Abstract
The following thermodynamic properties were determined for 1-pentene, 2-methyl-1-butene, and 2-methyl-2-butane: heats of vaporization at three temperatures, vapor heat capacities at five temperatures, vapor pressures and normal boiling points, second virial coefficients, values of (delta C/sub p//delta P)/sub T/, and the entropies of the vapors at three temperatures. A vibrational assignment was made for 2-methyl-2-butene, and the free energy function, heat content function, entropy and heat capacity of this substance were computed for selected temperatures up to 1500/sup 0/K, by statistical mechanical methods.