N. T. Brummelhuis, C. Diehl, H. Schlaad
Nov 7, 2008
Citations
0
Influential Citations
203
Citations
Quality indicators
Journal
Macromolecules
Abstract
Milder conditions would be desirable, especially when it comesto the synthesis of biohybrid samples containing amino acid,sugar, or cholesteryl entities (see Scheme 1). As will bedemonstrated, the thiol-ene modification of 1,2-PB can beperformed at low or ambient temperature employing UV lightor sunlight for a generation of thiyl radicals (in the absence ofphotoinitiator) and minimal amounts of solvent. Model reactionshave been performed with a 1,2-PB prepared by anionicpolymerization (