L. Suchomelová, V. Horák, J. Zýka
Jun 1, 1965
Citations
0
Influential Citations
2
Citations
Journal
Microchemical Journal
Abstract
Abstract Lead tetraacetate is a suitable volumetric reagent for the determination of organic sulfides in the medium of acetic acid. Conditions were found for the determination of about 10 to 50 mg of di-n-butyl-, di-sec-butyl- and n-butyl-phenyl sulfides with the use of the dead stop or constant current potentiometric method for the indication of the equivalence point. All types of sulfides can be determined with the use of this method; the reaction proceeds even in the case of tert-sulfides on the basis of the same mechanism. The result of the lower reactivity of tert-sulfides is a lower value.