Dominik Niedek, J. Wagner, P. Schreiner
Mar 1, 2017
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Influential Citations
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Journal
Journal of Analytical and Applied Pyrolysis
Abstract
Abstract Carbonothioic O,O-acid (monothiocarbonic acid), the sulfur analogue of carbonic acid, is thus far an experimentally unreported molecule of atmospheric and biochemical relevance. Computations at the CCSD(T)/cc-pVQZ//CCSD(T)/cc-pVTZ level of theory reveal that its carbonothioic O , S -acid tautomer is energetically favored over the carbonothioic O , O -acid tautomer and that the decomposition of the former to H 2 S and CO 2 is prevented by a barrier in excess of 30 kcal mol −1 . Therefore, we attempted to prepare carbonothioic- O,O -acid under matrix isolation conditions via high vacuum flash pyrolysis (HVFP) of O , S -di- tert -butyl carbonothioate in analogy to the previously reported successful preparation of carbonic acid. Pyrolysis at 900 °C only produced isobutene, CO 2 , and tert -buthylthiol, while S - tert -butyl O -hydrogen carbonothioate is the most likely additional product identifiable at 690 °C pyrolysis temperature. Density functional theory computations at the M06-2X/cc-pVTZ level were used to understand the pyrolysis pathways and help determine the leaving group ability in the ester pyrolysis step, and our inability to observe the carbonothioic acids via our chosen pyrolysis path.