Yuch-Hsiung Kuo, Yun-Lian Lin, E. Wang
Aug 1, 1996
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Journal
Journal of The Chinese Chemical Society
Abstract
8-Cedren-14-ol (4d) was oxidized with PCC, followed by autooxidation to yield 8,14-cedranolide (2a) and 8-cedren-14-carboxylic peracid (4e). 8β-Hydroxycedran-l3-al (1d) was subjected to autooxidation in three different solvents to give eight products, from which the transformation from cedrane skeleton to noracorane and decahydroazulene skeletons were observed. A free radical pathway was proposed.