M. F. Shostakovsky, N. A. Gershtein
1955
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Journal
Russian Chemical Bulletin
Abstract
1. A study has been made of the addition of 2-chloroethanol to alkyl vinyl ethers. 2. It has been shown that the reaction is brought about in a very simple manner — by mixing equimolecular amounts of the components—and is accompanied by an exothermic effect. 3. Five new alkyl 2-chloroethyl acetals have, been prepared: the 2-chloroethyl methyl, 2-chloroethyl propyl, 2-chloroethyl isopropyl, 2-chloroethyl isobutyl, and 2-chloroethyl isopentyl acetals of acetaldehyde. 4. These acetals, like other mixed acetals, are able to undergo disproportionation with formation of two symmetrical, dialkyl and bis(2-chloroethyl), acetals.