A. Ramasubramanian, R. Bhat, R. Dileep
2011
Citations
0
Influential Citations
13
Citations
Journal
Journal of The Serbian Chemical Society
Abstract
Transition metal complexes of 5-bromosalicylidene-4-amino-3-mer- capto-1,2,4-triazine-5-one with metal precursors, such as Cu(II), Ni(II), Co(II) and Pd(II), were synthesized and characterized by physico-chemical and spec- troscopic techniques. All the complexes are of the ML type. Based on analyti- cal, spectral data and magnetic moments, the Co(II) and Ni(II) complexes were assigned octahedral geometries, while the Cu (II) and Pd(II) complexes square planar. A study on the catalytic oxidation of benzyl alcohol, cyclohexanol, cin- namyl alcohol, 2-propanol and 2-methyl-1-propanol was performed with N- methylmorpholine-N-oxide (NMO) as co-oxidant. All the complexes and their parent organic moiety were screened for their biological activity on several pathogenic bacteria and were found to possess appreciable bactericidal pr- operties.