V. Dyakonov, G. N. Kadikova, U. Dzhemilev
Jul 30, 2018
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0
Influential Citations
12
Citations
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Journal
Russian Chemical Reviews
Abstract
The current review summarizes the published data on transition metal complex-mediated chemistry of 1,3,5-cycloheptatrienes. It addresses homodimerization of cycloheptatrienes and cyclocodimerization of the latter with alkenes, dienes and alkynes in the presence of transition metal complexes that occur via [2π + 2π], [3π + 2π], [6π + 2π], [6π + 4π] and [6π + 2π + 2π] cycloadditions. Special attention is given to the application of these reactions in the synthesis of valuable strained bi-, tri- and polycyclic compounds and for the development of methods of stereoselective synthesis of natural products. The bibliography includes 91 references.