A. S. Moskalenko, I. I. Chervin, A. V. Prosyanik
Mar 1, 1988
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Journal
Chemistry of Heterocyclic Compounds
Abstract
Primarily trans-1-chloroaziridine is formed in the chlorination of the potassium salt of aziridine-2,2-dicarboxylic acid methyl ester. The silver salt and then the mixed methyl ethyl ester, as well as the trimethylammonium and α-phenylethylammonium salts, were obtained from trans-1-chloroaziridine. Signals of diastereomers are observed in the PMR spectrum of the E isomer of the α-phenylethylammonium salt; this opens up the fundamental possibility of separation into antipodes.