A. Escuer, R. Vicente, J. Ribas
Apr 1, 1994
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Inorganic Chemistry
Abstract
The compounds trans-[Ni(333-tet)(μ-N 3 )] n (ClO 4 ) n (1) and cis-[Ni(333-tet)(μ-N 3 the tetraamine N,N'-bis(3-aminopropyl)-1,3-propanediamine have been synthesized and charactcrizcd. 1 crystallizes in the triclinic system, space group P1, with fw=388.50, a=8.765 (1) A, b=8.976 (1) A, c=11.995 (2) A, α=106.65(1) o , β=110.06(1) o , V=842.0(2) A 3 , Z=2, R=0.047, and R w =0.130. The nickel atom is placed in an octahedral environment with the bridging azido groups in a trans arrangement