C. Mahe, H. Patin, A. Benoit
Aug 11, 1981
Citations
0
Influential Citations
11
Citations
Journal
Journal of Organometallic Chemistry
Abstract
Abstract Reaction of dimethylthiocarbamoyl chloride or dimethylthioformamide with dicobalt octacarbonyl affords a new diamagnetic trinuclear cobalt carbonyl-sulfur complex SCo3(CO)7(CSNMe2) containing a bridging bidentate thiocarboxamido ligand liked to the cluster by a cobalt—carbon and a cobalt—sulfur bond. The structure has been determined by X-ray diffraction; comparison with the recently described SCo3(CO)7(μ-R1C-NR2) shows a different electronic distribution in the cluster and in the bridge, with important participation of the nitrogen atom.