J. Shapley, M. Tachikawa, M. Churchill
Dec 19, 1978
Citations
0
Influential Citations
17
Citations
Journal
Journal of Organometallic Chemistry
Abstract
The reaction of Os3 (CO)10(NCCH3)2 and triethylamine provides H2 Os3 (CO)10 and HOs3 (CO)10(CHCHNEt2) in equimolar amounts. The structure of the latter compound has been shown to involve an iminium ion center anchored to the Os3 framework by a bridging (substituted) methylene moiety.