Yuxia Zhao, Li Xiao, Feipeng Wu
May 1, 2007
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Influential Citations
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Journal
Optical Materials
Abstract
Abstract Two malononitrile derivatives, 2-[2,5-bis-(4-dimethylamino-benzylidene)-cyclopentylidene]-malononitrile ( 1 ) and 2-{2,6-bis-[2-(4-dimethylamino-phenyl)-vinyl]-pyran-4-ylidene}-malononitrile ( 2 ), were synthesized and their photophysical characteristics were investigated using UV–vis spectra, fluorescence spectra, nonlinear transmission and two-photon excited spectra. The results showed that both compounds exhibited strong intramolecular charge transfer absorption bands within 400–600 nm, but only compound 2 presented a strong fluorescence emission. By nonlinear transmission method, the two-photon absorption cross-section ( σ ) values of two compounds were determined as 250 GM and 283 GM, respectively, with 800 nm femtosecond laser pulses. By two-photon excited fluorescence method, the two-photon excited spectra of compound 2 within 720–880 nm was measured and its σ max was obtained as 773 GM at 770 nm.