Sayaka Ishii, Katsuya Saito, S. Kuwahara
Feb 24, 2021
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Bioscience, biotechnology, and biochemistry
Abstract
A Lewis acid-promoted nucleophilic addition of methallyltrimethylsilane to a chiral α-keto imide proceeded with stereoselectivity opposite to that predicted from Soai's report. The difference in the structure of α-keto imides between Soai's and our cases might have affected the diastereofacial selectivity.