Jing‐Yun Wu, P. Thanasekaran, Yi-Wei Cheng
Apr 11, 2008
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Influential Citations
25
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Journal
Organometallics
Abstract
An unprecedented partial reduction of 2,2′-bipyrimidine (bpym) occurred, affording the H6bpym2− moiety, during the one-pot self-assembly of neutral Re(I)-based molecular rectangles and bimetallic products under solvothermal conditions. Their structures were unambiguously characterized by 1H NMR and single-crystal X-ray diffraction analyses, and their electrochemical, electronic absorption, and photoluminescent properties were studied. The reaction pathway was also investigated.