Irina Novosjolova, M. Turks
Mar 16, 2015
Citations
0
Influential Citations
3
Citations
Journal
Phosphorus, Sulfur, and Silicon and the Related Elements
Abstract
GRAPHICAL ABSTRACT Abstract The synthesis of trimethylsilyl 2-methylprop-2-ene-1-sulfinate (Vogel's silyl sulfinate) from methallyltrimethylsilane and SO2 in the presence of Tf2NTMS was developed. The title compound silylates carbohydrates and other polyhydroxylated compounds by producing SO2 and isobutene as gaseous side products. This silylation procedure is perfectly suitable for derivatization and subsequent GC–MS quantitative analysis of ribose and malic acid as representatives of organic polyhydroxylated compounds.