A. Lagalante, R. J. Jacobson, T. Bruno
Sep 6, 1996
Citations
1
Influential Citations
26
Citations
Journal
The Journal of organic chemistry
Abstract
The potential of 4-nitropyridine N-oxide to act as a solvatochromic indicator of the hydrogen-bond donor ability of solvents has been evaluated. A linear free-energy relationship has been established that is predominantly dependent on the Kamlet-Taft alpha parameter of the solvent. In comparison to the previously reported results obtained for pyridine N-oxide, 4-nitropyridine N-oxide possesses a solvatochromic effect that is located in the long wavelength ultraviolet region (lambda = 330-355 nm) of the spectrum, making it a viable probe for hydrogen-bond donation assessment.