Y. Hoshino, Kenzō Suzuki, Kiyoshi Honda
Sep 13, 2012
Citations
0
Influential Citations
10
Citations
Journal
Synlett
Abstract
A general and efficient vanadium-catalyzed oxidation of tert-butyl N-hydroxycarbamate to tert-butyl nitrosoformate using alkyl hydroperoxides as terminal oxidants has been developed. The intermediate nitroso compound was trapped by in situ Diels–Alder reaction with simple and functionalized dienes, providing general access to a variety of functionalized 3,6-dihydro-2H-1,2-oxazines.