Xiutang Zhang, Liming Fan, Weiliu Fan
Feb 24, 2016
Citations
0
Influential Citations
17
Citations
Journal
Inorganica Chimica Acta
Abstract
Abstract Three 5-hydroxy isophthalic acid (H2OIP) based coordination polymers, namely, {[Cu(OIP)(bimb)]·H2O}n (1), {[Co2(OIP)2(bimb)2]·H2O}n (2), and [Zn(OIP)(bimb)]n (3) were synthesized under hydrothermal conditions in the presence of bis(imidazole) bridging linkers (bimb = 1,3-bis(1H-imidazol-4-yl)benzene (bimb)). Their structures have been determined by single-crystal X-ray diffraction analysis and further characterized by elemental analysis, IR spectra, powder X-ray diffraction (PXRD), and thermogravimetric (TG) analysis. Complex 1 displays a 3D ABAB packing supramolecular structure with 4-connected 2D wave sql sheet. Complex 2 possesses a 3D 5-connected bnn net based on [Co2(COO)2] secondary building unit (SBU) with a Schlafli symbol of (46·64). Complex 3 features a 2D flat sql net with Zn ions as 4-connected nodes. Moreover, the magnetic property of complex 2 and the solid state luminescence of complex 3 have been investigated.